Surface and inter-phase analysis of Composite Materials using Electromagnetic Techniques based on SQUID Sensors

In this thesis an electromagnetic characterization and a non-destructive evaluation of new advanced composite materials, Carbon Fiber Reinforced Polymers (CFRP) and Fiber-Glass Aluminium (FGA) laminates, using an eddy-current technique based on HTS dc-SQUID (Superconductive QUantum Interference Device) magnetometer is proposed. The main goal of this thesis is to propose a prototype based on a superconducting sensor, such as SQUID, to guarantee a more accuracy in the quality control at research level of the composite materials employed in the aeronautical applications. A briefly introduction about the superconductivity, a complete description of the SQUID properties and its basic working principles have been reported. Moreover, an overview of the most widely used non destructive technique employed in several industrial and research fields have been described. Particular attention is given to the eddy current testing and the technical improvement obtained using SQUID in NDE. The attention has been focused on two particular application, that are the main topics of this thesis. The first concerns with the investigation of the damage due to impact loading on the composites materials, and the second is the study of the corrosion process on the metallic surface. The electrical and mechanical properties of the tested advanced composite materials, such as Carbon Fiber Reinforced Polymers (CFRPs) and Fiber-glass Aluminium (FGA) laminates are investigated. The experimental results concern the non-destructive evaluation of impact loading on the CFRPs and FGA composites, by means of the electromagnetic techniques; the investigation of the electromechanical effect in the CFRPs using the SQUID based prototype and the AFM analyses; and the study of corrosion activity of the metallic surface using magnetic field measurement

Monitoring Composites under Bending Tests with Infrared Thermography

The attention of the present paper is focused on the use of an infrared imaging device to monitor the thermal response of composite materials under cyclic bending. Three types of composites are considered including an epoxy matrix reinforced with either carbon fibres (CFRP) or glass fibres (GFRP) and a hybrid composite involving glass fibres and aluminium layers (FRML). The specimen surface, under bending, displays temperature variations pursuing the load variations with cooling down under tension and warming up under compression; such temperature variations are in agreement with the bending moment. It has been observed that the amplitude of temperature variations over the specimen surface depends on the material characteristics. In particular, the presence of a defect inside the material affects the temperature distribution with deviation from the usual bending moment trend

Anomalous evolution of broadband optical absorption reveals dynamic solid state reorganization during eumelanin build-up in thin films

The origin of eumelanin optical properties remains a formidable conundrum preventing a detailed understanding of the complex photo-protective role of these widespread natural pigments and the rational design of innovative bioinspired materials for optoelectronic applications. Here we report the unusual kinetic and thickness-dependent evolution of the optical properties of black eumelanin polymers generated by spontaneous aerial polymerization of 5,6-dihydroxyindole (DHI) thin films (0.1-1 μm), consistent with peculiar solid state reorganization mechanisms governing broadband absorption. The complete reversal of eumelanin UV-visible transmittance spectrum curvature on passing from 0.2 to 0.5 μm thick films, the marked increase in visible extinction coefficients with increasing film thickness and the higher UV extinction coefficients in slowly vs. rapidly generated polymers concur to support distinct dynamic regimes of solid-state molecular reorganization at the nanoscale level and to do affect the development of broadband visible absorption. Solid state control of molecular reorganization disclosed herein may delineate new rational strategies for tuning optical properties in eumelanin thin films for optoelectronic applications

Detection of Magnetomechanical Effect in Structural Steel Using GMR 2nd Order Gradiometer Based Sensors

The magneto-mechanical behaviour of structural steel specimens stressed up to the plastic deformation stage was investigated using a 2nd order gradiometer based on Giant Magneto Resistive (GMR) sensors. The correlation between the gradient of the magnetization and the dislocation density before the crack initiation inside the test material was reported. The capability of the GMR scanning sensor to detect the residual magnetization due to the tensile stress with a non-invasive technique was demonstrated

Reduced graphene oxide on silicon-based structure as novel broadband photodetector

Heterojunction photodetector based on reduced graphene oxide (rGO) has been realized using a spin coating technique. The electrical and optical characterization of bare GO and thermally reduced GO thin films deposited on glass substrate has been carried out. Ultraviolet–visible–infrared transmittance measurements of the GO and rGO thin films revealed broad absorption range, while the absorbance analysis evaluates rGO band gap of about 2.8 eV. The effect of GO reduction process on the photoresponse capability is reported. The current–voltage characteristics and the responsivity of rGO/n-Si based device have been investigated using laser diode wavelengths from UV up to IR spectral range. An energy band diagram of the heterojunction has been proposed to explain the current versus voltage characteristics. The device demonstrates a photoresponse at a broad spectral range with a maximum responsivity and detectivity of 0.20 A/W and 7 × 10(10) cmHz/W, respectively. Notably, the obtained results indicate that the rGO based device can be useful for broadband radiation detection compatible with silicon device technology

Graphene–polymer coating for the realization of strain sensors

In this work we present a novel route to produce a graphene-based film on a polymer substrate. A transparent graphite colloidal suspension was applied to a slat of poly(methyl methacrylate) (PMMA). The good adhesion to the PMMA surface, combined with the shear stress, allows a uniform and continuous spreading of the graphite nanocrystals, resulting in a very uniform graphene multilayer coating on the substrate surface. The fabrication process is simple and yields thin coatings characterized by high optical transparency and large electrical piezoresitivity. Such properties envisage potential applications of this polymer-supported coating for use in strain sensing. The electrical and mechanical properties of these PMMA/graphene coatings were characterized by bending tests. The electrical transport was investigated as a function of the applied stress. The structural and strain properties of the polymer composite material were studied under stress by infrared thermography and micro-Raman spectroscopy

UV photo-responsivity of a large-area MWCNT-Si photodetector operated at cryogenic temperature

In the last decades much effort has been addressed to realize novel solid state photo-detectors with a high quantum efficiency in the UV wavelength region to be used in experiments detecting Cherenkov or fluorescence radiation even at cryogenic temperatures. Among the possible devices with these characteristics, the large-area solid detectors made of n-doped silicon substrate coated with Multi-Walled Carbon Nanotubes (MWCNTs) appear to be particularly promising since they combine the great UV radiation absorbance of MWCNTs (at about 200 nm) with their unique characteristics for electrical conductivity and mechanical resistance at low temperatures. In this work we present the cryogenic characteristics of a MWCNT-Si large-area (1 cm2) photo-detector, in which a UV photo-sensitive heterojunction is obtained growing, by Chemical Vapour Deposition (CVD), multi-walled carbon nanotubes on an n-type silicon substrate. Measurements have been made at various temperatures in the range from 5K to 300K by illuminating the photo-detector with a 378 nm UV continuous laser light source. Results demonstrate the capability of such device to be successfully employed in cryogenic experiments as well at room temperature with high stability and high photon detection efficiency in the UV region

Design and performance of the prototype Schwarzschild-Couder telescope camera

International audienceThe prototype Schwarzschild-Couder Telescope (pSCT) is a candidate for a medium-sized telescope in the Cherenkov Telescope Array. The pSCT is based on a dual-mirror optics design that reduces the plate scale and allows for the use of silicon photomultipliers as photodetectors. The prototype pSCT camera currently has only the central sector instrumented with 25 camera modules (1600 pixels), providing a 2.68-deg field of view (FoV). The camera electronics are based on custom TARGET (TeV array readout with GSa/s sampling and event trigger) application-specific integrated circuits. Field programmable gate arrays sample incoming signals at a gigasample per second. A single backplane provides camera-wide triggers. An upgrade of the pSCT camera that will fully populate the focal plane is in progress. This will increase the number of pixels to 11,328, the number of backplanes to 9, and the FoV to 8.04 deg. Here, we give a detailed description of the pSCT camera, including the basic concept, mechanical design, detectors, electronics, current status, and first light